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Frank Hörmann and Prof. Dr. Andreas Hirsch Giant Fullerene Polyelectrolytes Composed of C60 Building Blocks with an Octahedral Addition Pattern and Discovery of a New Cyclopropanation Reaction Involving Dibromomalonates Chemistry - A European Journal 19

Article first published online: 17 JAN 2013 | DOI: 10.1002/chem.201203881

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On the shoulders of giants: A giant heptafullerene (see figure) is one of four new prototypes of large fullerene-based polyelectrolytes with a precisely defined structure. The key intermediates for the construction of these macromolecules were synthesized from the C2v-symmetrical pentakisadducts in excellent yields.

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