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Dr. Joel F. Hooper, Dr. Rowan D. Young, Prof. Andrew S. Weller and Dr. Michael C. Willis Traceless Chelation-Controlled Rhodium-Catalyzed Intermolecular Alkene and Alkyne Hydroacylation Chemistry - A European Journal 19

Version of Record online: 16 JAN 2013 | DOI: 10.1002/chem.201204056

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Traceless catalysis: The powerful combination of a chelation-controlled hydroacylation process and a new rhodium-catalyzed sulfide reduction gave the products of traceless hydroacylation. Aryl- and alkenyl aldehydes can be combined with alkenes, alkynes, and allenes to deliver traceless products in high yields (see scheme).

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