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Dr. Martha V. Escárcega-Bobadilla, Dr. Marta Martínez Belmonte, Eddy Martin, Eduardo C. Escudero-Adán and Prof. Dr. Arjan W. Kleij A Recyclable Trinuclear Bifunctional Catalyst Derived from a Tetraoxo Bis-Zn(salphen) Metalloligand Chemistry - A European Journal 19

Version of Record online: 25 JAN 2013 | DOI: 10.1002/chem.201204132

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A recyclable threesome: Highly stable supramolecular trinuclear complexes have been derived from a bis-Zn(salphen) metalloligand in almost quantitative yield and can act as bifunctional catalysts in the synthesis of organic carbonates from epoxides and CO2 under solvent-free conditions. These complexes have high recycling potential and can be used in up to five cycles without significant loss in substrate conversion and product yield.

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