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Chawanwit Kumsapaya, Marie-France Bakaï, Dr. Gabriel Loget, Bertrand Goudeau, Dr. Chompunuch Warakulwit, Prof. Jumras Limtrakul, Prof. Alexander Kuhn and Dr. Dodzi Zigah Wireless Electrografting of Molecular Layers for Janus Particle Synthesis Chemistry - A European Journal 19

Version of Record online: 28 DEC 2012 | DOI: 10.1002/chem.201204198

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Glassy carbon beads are selectively functionalized on one side with an ultrathin organic layer by bipolar electrochemical reduction of diazonium salts to give Janus-type beads with a hybrid organic–inorganic composition (see scheme). The presence of the grafted organic layers is revealed either by co-adsorption of gold nanoparticles or by coupling with a fluorescent molecule.

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