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Ross S. Winter, Dr. Jun Yan, Dr. Christoph Busche, Dr. Jennifer S. Mathieson, Dr. Alessandro Prescimone, Prof. Euan K. Brechin, Dr. De-Liang Long and Prof. Leroy Cronin Nanoscale Control of Polyoxometalate Assembly: A {Mn8W4} Cluster within a {W36Si4Mn10} Cluster Showing a New Type of Isomerism Chemistry - A European Journal 19

Version of Record online: 30 JAN 2013 | DOI: 10.1002/chem.201204345

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Nanoassembly: Assembly isomers of a {Mn8W4} Keggin cluster within a [W36Mn10Si4O136(OH)4(H2O)8]24− cluster are reported. The clusters are formed through the aggregation of new {γ-SiMnW9} fragments in a tetrahedral fashion. Investigation of the crystal growth of these clusters revealed two intermediate clusters, which unveiled a mechanism of formation (see scheme). Physical analysis of the magnetic and solution behaviour of the isomers is also reported.

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