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Dr. Simone Raugei, Dr. Shentan Chen, Dr. Ming-Hsun Ho, Dr. Bojana Ginovska-Pangovska, Dr. Roger J. Rousseau, Dr. Michel Dupuis, Dr. Daniel L. DuBois and Dr. R. Morris Bullock Inside Cover: The Role of Pendant Amines in the Breaking and Forming of Molecular Hydrogen Catalyzed by Nickel Complexes (Chem. Eur. J. 21/2012) Chemistry - A European Journal 18

Version of Record online: 15 MAY 2012 | DOI: 10.1002/chem.201290084

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Pendant amines incorporated in the second coordination sphere of nickel bis(diphosphine) catalysts for H2 oxidation and H2 production play a crucial role in the breaking and forming of the H[BOND]H bond of molecular hydrogen. An accurate and comprehensive theoretical study is reported in the Full Paper by S. Raugei et al. on page 6493 ff., which allows for a deeper atomistic understanding, that will guide the design of more efficient electrocatalysts for the intercorversion between electrical energy and fuels.

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