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Joel Malmgren, Dr. Stefano Santoro, Dr. Nazli Jalalian, Prof. Fahmi Himo and Prof. Berit Olofsson Arylation with Unsymmetrical Diaryliodonium Salts: A Chemoselectivity Study Chemistry - A European Journal 19

Version of Record online: 20 JUN 2013 | DOI: 10.1002/chem.201300860

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Salts with a choice: Phenols, anilines, and malonates were arylated under metal-free conditions with several aryl(phenyl)iodonium salts (see scheme). DFT calculations have been performed to investigate the reaction mechanism and elucidate the origins of the observed selectivities.

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