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Christine Kallweit, Prof. Dr. Gebhard Haberhauer and Sascha Woitschetzki 4,4′-Bipyridine as a Unidirectional Switching Unit for a Molecular Pushing Motor Chemistry - A European Journal 20

Version of Record online: 8 APR 2014 | DOI: 10.1002/chem.201304166

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Motor drive: The combination of the intrinsic chirality of a 4,4′-bipyridine with a metal-ion-induced switching principle leads to a metal-ion-induced chirality switch that can also be used as a basic unit for a molecular pushing motor. Rotation around the C[BOND]C bond axis of the bipyridine, which is linked to a cyclic imidazole peptide, leads to switching between P and M isomers (see scheme).

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