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Chen Wang and Lei Liu Mechanism of Imidazole-Promoted Ligation of Peptide Phenyl Esters Chinese Journal of Chemistry 30

Version of Record online: 11 JUL 2012 | DOI: 10.1002/cjoc.201200337

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Theoretical calculations successfully explain that for a sterically hindered C-terminal amino acid (e.g. proline), the imidazole-promoted phenyl ester ligation is more favorable than the conventional thiophenol-promoted native chemical ligation.

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