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Bin Liu, Qianyi Zhao, Huijuan Wang, Jinxiang Chen, Xiaoyu Cao, Zexing Cao and Haiping Xia Synthesis of Osmapyridiniums by [4+2] Cycloaddition Reaction between Osmium Alkenylcarbyne and Nitriles Chinese Journal of Chemistry 30

Version of Record online: 25 SEP 2012 | DOI: 10.1002/cjoc.201200650

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A formal [4+2] cycloaddition reaction between osmium alkenylcarbyne and nitriles was used to provide metallapyridiniums. These metallapyridiniums can be readily transformed to other metallapyridiniums by ligand substitution reaction, thus expanding the scope of still rare heteroatom-containing aromatic metallacycles.

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