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Yong Ye, Yanhua Wang, Pengtang Liu and Fushe Han Cu2O-Mediated Room Temperature Cyanation of Aryl Boronic Acids/Esters and TMSCN Chinese Journal of Chemistry 31

Article first published online: 11 DEC 2012 | DOI: 10.1002/cjoc.201200711

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A method for the efficient and reliable synthesis of aryl nitriles via the Cu2O-catalyed cross-coupling of aryl boronic acids or esters and TMSCN is presented. The room temperature operation paired with the use of cheap, readily available, and halogen-free Cu2O as catalysts makes the protocol an appealing option for aryl cyanations.

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