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Hongli Bao, Zheng Wang, Tianpa You and Kuiling Ding Enantioselective Ring Opening of meso-Epoxides with Aromatic Amines Catalyzed by Dinuclear Magnesium Complexes Chinese Journal of Chemistry 31

Article first published online: 27 DEC 2012 | DOI: 10.1002/cjoc.201201008

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Dinuclear Mg complexes generated in situ from the combination of phenol-bridged bis(α,α-diarylprolinol) ligands and n-Bu2Mg were found to be efficient for the catalytic asymmetric ring opening of meso-epoxides with aniline derivatives as nucleophiles, affording the corresponding chiral β-amino alcohols in good yields with up to 90% ee.

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