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Lili Zhu and Ran Hong Biomimetic Cationic Cyclization toward ent-Kaurene-type Diterpenoids Chinese Journal of Chemistry 31

Version of Record online: 8 JAN 2013 | DOI: 10.1002/cjoc.201201029

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A chiral acetal-enabled and SnCl4-promoted biomimetic polyene cationic cyclization was followed by oxidation and a cascade process of Birch reduction and alkylation to complete a core skeleton of representative ent-kaurene diterpenoids.

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