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Kui Wu, Meining Wang, Qizheng Yao and Ao Zhang Synthesis Study toward Mayamycin Chinese Journal of Chemistry 31

Version of Record online: 8 JAN 2013 | DOI: 10.1002/cjoc.201201084

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Natural product mayamycin is the first example in the angucycline class featuring a C-glycoside linkage at the C5-position of the benz[a]anthracenone core with remarkable biological activities. We successfully synthesized the two retrosynthetic fragments, but the final C-glycosylation did not occur. Instead, a two-ring less analog was success fully prepared, suggesting the steric effect played an important role in the synthesis of mayamycin.

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