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Jie Zhang, Zengqiang Jiang, Dan Zhao, Guozhen He, Shuangli Zhou and Shiqing Han Transition-Metal-Free TEMPO Catalyzed Aerobic Oxidation of Alcohols to Carbonyls Using an Efficient Br2 Equivalent under Mild Conditions Chinese Journal of Chemistry 31

Article first published online: 21 MAY 2013 | DOI: 10.1002/cjoc.201300052

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An effective transition-metal-free catalytic system is developed for aerobic oxidations of alcohols. Using catalytic amount of bromide-bromate coupling, H2SO4, and NaNO2, together with 2,2,6,6-tetramethylpiperidine N-oxyl radical (TEMPO) in the presence of air, various alcohols could be converted into the corresponding aldehydes or ketones in good to excellent isolated yields under mild conditions.

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