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Dr. Nan Jiang  and Prof. Jing Ma Can a Proton be Encapsulated in Tetraamido/Diamino Quaternized Macrocycles in Aqueous Solution and Electric Field? ChemPhysChem 12

Version of Record online: 17 AUG 2011 | DOI: 10.1002/cphc.201100229

Thumbnail image of graphical abstract

Proton encapsulation in water-solvated tetraamido/diamino quaternized macrocycles depends on whether the bridge linkages are rigid (phenyl) or flexible (propyl) and the influence of an external electric (E) field. When an E field is applied, the proton migrates from the macrocyclic framework to the water in the former case, but it can still be encapsulated in the latter (see picture).

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