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Dr. Po-Yu Tsai and Prof. King-Chuen Lin Rotational Energy Transfer of SH(X2Π, v′′=0, J′′=0.5–10.5) by Collision with Ar: Λ-Doublet Resolved Transition Propensity ChemPhysChem 13

Version of Record online: 26 OCT 2011 | DOI: 10.1002/cphc.201100604

Thumbnail image of graphical abstract

Collision-induced transitions: The picture shows Λ-doublet resolved RET rotational energy transfer rate constants for SH(X2Π, v′′=0) by collision with Ar for the transitions within F1 or F2 manifolds with initial J=1.5 or 0.5 (see picture) and for the transitions between F1 and F2 manifolds with initial J=2.5, 7.5, or 0.5. In general, the Π(A′) final level is preferred, irrespective of the initial e/f symmetry, in all collision-induced transitions, except those from F2 to F1 levels.

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