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Zijuan Hao, Xingcui Wu, Ranran Sun, Prof. Changqin Ma and Prof. Xiaomei Zhang Morphology Controlled Nanostructures Self-Assembled from Phthalocyanine Derivatives Bearing Alkylthio Moieties: Effect of Sulfur–Sulfur and Metal–Ligand Coordination on Intermolecular Stacking ChemPhysChem 13

Article first published online: 12 DEC 2011 | DOI: 10.1002/cphc.201100612

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Nanobelts, nanoribbons, and nanoflowers are formed by aggregation of 2,3,9,10,16,17,23,24-octakis(isopropylthio)phthalocyanine H2Pc(β-SC3H7)8, CuPc(β-SC3H7)8, and PbPc(β-SC3H7)8, respectively (see picture). π–π interactions, intermolecular sulfur–sulfur interactions and metal–ligand coordination bonding compete for different nanostructure morphologies in the self-assembly process.

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