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Juan Aragó, Dr. Rocío Ponce Ortiz , Belén Nieto-Ortega, Prof. Víctor Hernández, Prof. Juan Casado, Prof. Antonio Facchetti, Prof. Dr. Tobin J. Marks, Prof. Dr. Pedro M. Viruela, Prof. Dr. Enrique Ortí and Prof. Dr. Juan T. López Navarrete Carbonyl-Functionalized Quaterthiophenes: A Study of the Vibrational Raman and Electronic Absorption/Emission Properties Guided by Theoretical Calculations ChemPhysChem 13

Version of Record online: 1 DEC 2011 | DOI: 10.1002/cphc.201100736

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A cross-conjugated pathway arising from the presence of a central carbonyl group in the quaterthiophene backbone results in quite distinct structural and electronic properties compared to C[BOND]C/C[DOUBLE BOND]C linearly conjugated quaterthiophenes, as revealed by a study of carbonyl-functionalized quaterthiophenes by Raman (see picture), UV/Vis spectroscopy and quantum-chemical calculations.

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