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Gitanjali Rai and Dr. Anil Kumar  Probing Thermal Interactions of Ionic Liquids with Dimethyl Sulfoxide ChemPhysChem 13

Version of Record online: 16 FEB 2012 | DOI: 10.1002/cphc.201100821

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Excess partial molar enthalpies of ionic liquids (ILs) equation image in DMSO are determined by isothermal titration calorimetry and used to probe IL/DMSO interactions. Protic ILs such as 1-methylimidazolium tetrafluoroborate (equation image>1) tend to remain in the ionic form in DMSO, whereas aprotic ILs like 1-butyl-3-methylimidazolium tetrafluoroborate (equation image≈1) tend to form ion pairs (see picture).

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