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Dr. Francesca D'Anna, Dr. Salvatore Marullo, Paola Vitale and Prof. Renato Noto Binary Mixtures of Ionic Liquids: A Joint Approach to Investigate their Properties and Catalytic Ability ChemPhysChem 13

Article first published online: 9 FEB 2012 | DOI: 10.1002/cphc.201100878

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Mixing two ionic liquids (ILs) affects the outcome of reactions such as mononuclear rearrangement of a heterocycle (MRH) and solvatochromism of Nile Red. Greater changes in the ionic lattice are found when an IL mixture contains different anions. In mixture M1 the rate constant kobs(MRH) increases with increasing mole fraction X of the second IL, but shows a bell-like curve for M2 (see picture).

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