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Dr. Dzmitry H. Zaitsau, Dr. Koichi Fumino, Dr. Vladimir N. Emel'yanenko, Andrei V. Yermalayeu, Prof. Ralf Ludwig  and Prof. Sergey P. Verevkin Structure–Property Relationships in Ionic Liquids: A Study of the Anion Dependence in Vaporization Enthalpies of Imidazolium-Based Ionic Liquids ChemPhysChem 13

Version of Record online: 1 FEB 2012 | DOI: 10.1002/cphc.201100879

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Depend or not depend: The quartz crystal microbalance and far-IR spectroscopy are used to determine vaporization enthalpies, ΔlgH°m, for a series of ionic liquids (ILs) [C2mim][X] (see picture). Dependences of vaporization enthalpies on physicochemical parameters specific for anions are revealed and a simple group-contribution method is developed for predicting vaporization enthalpies of alkyl imidazolium-based ILs.

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