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Angela Ulbrich, Markus Reinmöller, Dr. Wichard J. D. Beenken and Dr. Stefan Krischok Surface Electronic Structure of [XMIm]Cl Probed by Surface-Sensitive Spectroscopy ChemPhysChem 13

Version of Record online: 19 APR 2012 | DOI: 10.1002/cphc.201100972

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Buried beneath the cations alkyl chain: In this study, photoelectron spectroscopy (XPS and UPS) and metastable induced electron spectroscopy (MIES), which feature individual surface-sensitivities, have been compared with reconstructions of valence band spectra from single ion pair calculations. The chlorine anion in a set of ionic liquids ([XMIm]Cl) has been identified to be displaced from the ionic liquid-vacuum-interface.

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