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Dr. Osama Y. Ali, Nicholas M. Randell and Prof. Dr. Travis D. Fridgen Primary Fragmentation Pathways of Gas Phase [M(Uracil−H)(Uracil)]+ Complexes (M=Zn, Cu, Ni, Co, Fe, Mn, Cd, Pd , Mg, Ca, Sr, Ba, and Pb): Loss of Uracil versus HNCO ChemPhysChem 13

Version of Record online: 23 MAR 2012 | DOI: 10.1002/cphc.201200015

Thumbnail image of graphical abstract

Uracil binding energies of complexes [M(Uracil−H)(Uracil)]+ (M=Zn, Cu, Ni, Co, Fe, Mn, Cd, Pd, Mg, Ca, Sr, Ba, or Pb), which are studied by mass spectrometry and DFT, correlate with metal-ion size (see picture). The primary decomposition pathway is loss of HNCO, except for the largest cations (M=Ca, Sr, Ba, or Pb), for which the more weakly bound uracil ligand is lost.

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