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Dr. Safak Bulut, M. A. Ab Rani, Prof. Dr. Tom Welton, Prof. Dr. Paul D. Lickiss and Prof. Dr. Ingo Krossing Preparation of [Al(hfip)4]−-Based Ionic Liquids with Siloxane-Functionalized Cations and Their Physical Properties in Comparison with Their [Tf2N]− Analogues ChemPhysChem 13

Version of Record online: 12 MAR 2012 | DOI: 10.1002/cphc.201200028

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Get over your size: We present fast and practical syntheses of two [Al(hfip)4]-ionic liquids (ILs) with siloxane-functionalized cations (see picture). Temperature-dependent viscosities and conductivities of [Al(hfip)4]-ILs in comparison with their [Tf2N] analogues reveal that the anion effectively remove the influence of the cation size on the IL properties.

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