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Dongdong Qi, Lijuan Zhang, Luyang Zhao, Dr. Xue Cai and Prof. Dr. Jianzhuang Jiang A Special Conjugated Model around sp3 Carbon Atoms: Density Functional Theory Study on the Homoaromatic Electron Delocalization and Applications of Benzo-Fused Tetra(triptycene)porphyrins ChemPhysChem 13

Version of Record online: 29 MAR 2012 | DOI: 10.1002/cphc.201200076

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Three′s a crowd: The three-unit homoaromatic electron-delocalizing nature of the benzo-fused tetra(triptycene)porphyrins with a three-dimensional conjugated model is clarified using density functional theory (see picture). The potential applications of the compounds in the fields of solar antenna collectors and host–guest chemistry are discussed.

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