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Prof. Sergey A. Katsyuba, Dr. Elena E. Zvereva, Dr. Ning Yan, Xiao Yuan , Prof. Yuan Kou and Prof. Paul J. Dyson Rationalization of Solvation and Stabilization of Palladium Nanoparticles in Imidazolium-Based Ionic Liquids by DFT and Vibrational Spectroscopy ChemPhysChem 13

Version of Record online: 23 MAR 2012 | DOI: 10.1002/cphc.201200087

Thumbnail image of graphical abstract

Both anions and cations of 1,3-dialkylimidazolium tetrafluoroborates interact with Pd nanoparticles (Pd-NPs) in ionic liquids according to a combined DFT/vibrational spectroscopy study involving, among other things, IL-stabilised Pd-NPs (see picture) and adducts of Pdn clusters as NP models with IL components, such as the Pd5–[1,3-dialkylimidazolium]3[BF]2+ adduct (inset).

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