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Prof. Dr. Eric Vauthey Photoinduced Symmetry-Breaking Charge Separation ChemPhysChem 13

Article first published online: 30 MAR 2012 | DOI: 10.1002/cphc.201200106

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Fearful symmetry: In some molecular systems, two or more apparently equivalent charge separation pathways exist upon photoexcitation (see picture). In all cases, charge separation involves symmetry breaking. The conditions for such process to be operative as well as the origin of the symmetry breaking are discussed.

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