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Prof. Dr. Vladimir S. Pavlovich Solvatochromism and Nonradiative Decay of Intramolecular Charge-Transfer Excited States: Bands-of-Energy Model, Thermodynamics, and Self-Organization ChemPhysChem 13

Version of Record online: 9 NOV 2012 | DOI: 10.1002/cphc.201200426

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Matters of state: A bands-of-energy stochastic model and principles of thermodynamics and self-organization of systems are used to gain insight into the nature of solvatochromism and photoinduced orientation relaxation in the excited and ground states of fluorophores. The findings on solvatochromic shift and spectral broadening allow calculation of solvent effects on the rate constant knr of nonradiative transitions S1[RIGHTWARDS ARROW]Xn (see picture; IC=internal conversion).

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