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Dr. Rachel Crespo-Otero, Dr. Artur Mardyukov, Dr. Elsa Sanchez-Garcia, Dr. Mario Barbatti and Prof.Dr. Wolfram Sander Photochemistry of N-Methylformamide: Matrix Isolation and Nonadiabatic Dynamics ChemPhysChem 14

Version of Record online: 2 OCT 2012 | DOI: 10.1002/cphc.201200573

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Finding Neo: Irradiation of trans N-methylformamide in an argon matrix produces the CH3NH2⋅⋅⋅CO complex and the cis isomer as major products (see picture). The mechanism is explained by using nonadiabatic dynamics.

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