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Rafael C. González Cano, Helena Herrera, Prof. José L. Segura, Prof. Juan T. López Navarrete, Dr. M. Carmen Ruiz Delgado and Prof. Juan Casado Conformational Control of the Electronic Properties of an α-β Terthiophene: Lessons from a Precursor Towards Dendritic Hyperbranched Oligo- and Poly-Thiophenes ChemPhysChem 13

Article first published online: 30 AUG 2012 | DOI: 10.1002/cphc.201200620

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Conformational flexibility of α–β oligothiophenes is scrutinized by Raman spectroscopy and DFT calculations (see picture). Structural and photonic properties are addressed through the interplay among the conformers in terms of π conjugation, ΔE0 and ΔE≈0 energies.

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