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Dr. Wenjian Tang, Hongmei Zhou, Jing Wang, Chunxiao Pan, Dr. Jingbo Shi and Prof. Qinhua Song Substituent Effects on Photosensitized Splitting of Thymine Cyclobutane Dimer by an Attached Indole ChemPhysChem 13

Article first published online: 4 OCT 2012 | DOI: 10.1002/cphc.201200652

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Two reverse solvent effects were observed in a series of indole–cyclobutane pyrimidine dimer model systems with differently substituted indole moieties. Thus, the splitting quantum yield Φspl shows a normal relation with solvent polarity for compounds with an electron-donating group, and vice versa for those with an electron-withdrawing group (see picture; bet=back electron transfer).

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