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Katarzyna Grzechnik, Dr. Krzysztof Mierzwicki and Dr. Zofia Mielke Matrix-Isolated Hydrogen-Bonded and Van der Waals Complexes of Hydrogen Peroxide with OCS and CS2 ChemPhysChem 14

Version of Record online: 7 NOV 2012 | DOI: 10.1002/cphc.201200696

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The weak H2O2 complexes with OCS and CS2 are sensitive to the environment. In solid argon at least two types of the complexes are formed of the four possible OCS and five CS2 ones. The solid nitrogen environment triggers the formation of the other structures with OCS or CS2 molecule perpendicular to the O[BOND]O bond of H2O2.

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