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Dr. Martin Weiler, Takashi Nakamura, Prof. Dr. Hiroshi Sekiya, Prof. Dr. Otto Dopfer, Prof. Dr. Mitsuhiko Miyazaki and Prof. Dr. Masaaki Fujii Ionization-Induced Solvent Migration in Acetanilide-Methanol Clusters Inferred from Isomer-Selective Infrared Spectroscopy ChemPhysChem 13

Article first published online: 30 OCT 2012 | DOI: 10.1002/cphc.201200704

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Put the solvent in seven-league boots: Ionization-induced methanol migration around a peptide linkage is observed in acetanilide-methanol clusters. Upon photoionization the methanol ligand is released from the CO site and trapped at the NH site of the amide group. Isomer-selective IR spectroscopy in the S0, S1, and cation (D0) states reveal an ionization-induced CO[RIGHTWARDS ARROW]NH migration.

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