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Tao Liang, Dr. Paul L. Raston and Prof. Gary E. Douberly Helium Nanodroplet Isolation Spectroscopy and ab Initio Calculations of HO3[BOND](O2)n Clusters ChemPhysChem 14

Version of Record online: 9 NOV 2012 | DOI: 10.1002/cphc.201200712

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One drop at a time: Complexes between dioxygen and the hydrotrioxy radical (hydridotrioxygen: HOOO) are assembled in low-temperature helium nanodroplets. IR laser spectroscopy and ab initio calculations reveal the structures of these radical cluster systems (see picture), which are exit channel complexes in the reaction HO2+O3[RIGHTWARDS ARROW]HO3+O2.

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