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Prof. Yoshiya Inokuchi, Dr. Ryoji Kusaka, Prof. Takayuki Ebata, Dr. Oleg V. Boyarkin and Prof. Thomas R. Rizzo Laser Spectroscopic Study of Cold Host–Guest Complexes of Crown Ethers in the Gas Phase ChemPhysChem 14

Version of Record online: 30 NOV 2012 | DOI: 10.1002/cphc.201200746

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In the cold: The structure of cold inclusion complexes of crown ethers (CEs) with various neutral and ionic species in the gas phase is reported (see figure). By the combination of laser spectroscopy and theoretical analysis, details of the interaction energy and importance of the flexibility of CEs for the formation of unique complex structures as well as molecular recognition are discussed.

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