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Dr. Christian Merten and Prof. Dr. Yunjie Xu Matrix Isolation-Vibrational Circular Dichroism Spectroscopy of 3-Butyn-2-ol and its Binary Aggregates ChemPhysChem 14

Article first published online: 25 OCT 2012 | DOI: 10.1002/cphc.201200758

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Good vibrations: Good mirror-image matrix isolation-vibrational circular dichroism (MI-VCD) spectra of the two enantiomers of 3-butyn-2-ol are achieved in low-temperature matrices (see picture). The well-resolved experimental MI-VCD bands provide the essential mean to assign associated vibrational absorption spectral features correctly. By varying the matrix temperature, it is possible to follow the self-aggregation of the chiral alcohol.

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