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Matthias Schmies, Alexander Patzer, Sarah Kruppe, Prof. Dr. Mitsuhiko Miyazaki, Prof. Dr. Shun-ichi Ishiuchi, Prof. Dr. Masaaki Fujii and Prof. Dr. Otto Dopfer Microsolvation of the 4-Aminobenzonitrile Cation (ABN+) in a Nonpolar Solvent: IR Spectra of ABN+[BOND]Ln (L=Ar and N2, n≤4) ChemPhysChem 14

Article first published online: 3 DEC 2012 | DOI: 10.1002/cphc.201200790

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Solvent binding: Site switching from π[RIGHTWARDS ARROW]H in the preferred ligand-binding motif upon ionization is observed for the interaction of 4-aminobenzonitrile (ABN) with nonpolar ligands by a combination of IR spectroscopy and quantum chemical calculations (see picture).

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