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Dr. Ke Feng, Dr. Mao-Lin Yu, Dr. Su-Min Wang, Dr. Ge-Xia Wang, Prof. Dr. Chen-Ho Tung and Prof. Dr. Li-Zhu Wu Photoinduced Triplet–Triplet Energy Transfer in a 2-Ureido-4(1H)-Pyrimidinone-Bridged, Quadruply Hydrogen-Bonded Ferrocene–Fullerene Assembly ChemPhysChem 14

Version of Record online: 30 NOV 2012 | DOI: 10.1002/cphc.201200818

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Unexpectedly effective intra-assembly triplet–triplet energy transfer is revealed in the depicted 2-ureido-4(1H)-pyrimidinone-bridged ferrocene–fullerene assembly by steady-state and time-resolved spectroscopy, whereas the electron-transfer process from the ferrocene to the singlet or triplet excited state of the fullerene is inefficient, although the electron-transfer reactions are thermodynamically feasible.

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