E-mail a Wiley Online Library Link

Jørgen Houmøller, Sydney H. Kaufman, Dr. Kristian Støchkel, Prof. Lokesh C. Tribedi, Prof. Steen Brøndsted Nielsen and Prof. J. Mathias Weber On the Photoabsorption by Permanganate Ions in Vacuo and the Role of a Single Water Molecule. New Experimental Benchmarks for Electronic Structure Theory ChemPhysChem 14

Version of Record online: 1 FEB 2013 | DOI: 10.1002/cphc.201300019

Thumbnail image of graphical abstract

New light on permanganate: Electronic spectra of MnO4 and its complex with a single water molecule are measured in vacuo by photodissociation action spectroscopy of the mass-selected parent ions. The spectra are red-shifted by 0.15 eV compared to the spectrum obtained for the ions in aqueous solution. The data provide the best experimental benchmarks for electronic structure calculations on these prototypical metal tetroxo ions.

Complete the form below and we will send an e-mail message containing a link to the selected article on your behalf

Required = Required Field