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Dr. Magdalena Gebala, Dr. Fabio La Mantia and Prof. Dr. Wolfgang Schuhmann Kinetic and Thermodynamic Hysteresis Imposed by Intercalation of Proflavine in Ferrocene-Modified Double-Stranded DNA ChemPhysChem 14

Version of Record online: 14 MAY 2013 | DOI: 10.1002/cphc.201300045

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DNA-bound ferrocene (Fc) undergoes rapid electron transfer with the electrode surface, which is sensitive to the ion transport along the DNA strands—a phenomenon that is modulated upon specific intercalation of proflavine into double-stranded DNA (dsDNA). The electron-transfer rate of the Fc/Fc+ redox process is influenced by the cationic permselectivity of the DNA monolayer.

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