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Qiang Li, Yan-Ni Li, Tao Wang, Dr. Sheng-Guang Wang, Chun-Fang Huo, Dr. Yong-Wang Li, Dr. Jianguo Wang and Dr. Haijun Jiao Electronic Structures and Energies of Fe2(CO)n (n=0–9) ChemPhysChem 14

Version of Record online: 19 MAR 2013 | DOI: 10.1002/cphc.201300076

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The most stable unsaturated Fe2(CO)n (n=1–8) complexes have terminal carbonyls. A stepwise CO coordination takes place first on one Fe center [Fe[BOND]Fe(CO)4] and then on the second one [(CO)4Fe[BOND]Fe(CO)4].

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