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Stefan Berdzinski, Joachim Horst, Petra Straßburg and Prof. Dr. Veronika Strehmel Recombination of Lophyl Radicals in Pyrrolidinium-Based Ionic Liquids ChemPhysChem 14

Version of Record online: 6 MAY 2013 | DOI: 10.1002/cphc.201300098

Thumbnail image of graphical abstract

Rate increases: Long alkyl chains bound at the cation of 1-alkyl-1-methylpyrrolidinium bis(trifluoromethylsulfonyl)imide ionic liquids change the steric requirements on the transition state of the bimolecular lophyl radical recombination reaction (see picture). Recombination of the photolytically generated radicals is faster in the ionic liquids than in traditional organic solvents.

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