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Dr. Ivan E. Kareev, Dr. Elena Laukhina, Dr. Vyacheslav P. Bubnov, Dr. Vyacheslav M. Martynenko, Vega Lloveras, Dr. José Vidal-Gancedo, Dr. Marta Mas-Torrent, Prof. Jaume Veciana and Prof. Concepció Rovira Harnessing Electron Transfer from the Perchlorotriphenylmethide Anion to Y@C82(C2v) to Engineer an Endometallofullerene-Based Salt ChemPhysChem 14

Article first published online: 28 MAR 2013 | DOI: 10.1002/cphc.201300107

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Add a pinch of salt: A [Y@C82(C2v)]-based salt with a complex cation is prepared in high yield by reacting Y@C82(C2v) with the [K+([18]crown-6)]PTM salt (PTM=perchlorotriphenylmethide anion; see picture); this ionic Y@C82-based compound reveals outstanding stability in solution and in the solid state.

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