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Dr. Camilla Calabrese, Dr. Assimo Maris, Dr. Luca Evangelisti, Prof. Walther Caminati and Prof. Sonia Melandri Fluorine Substitution Effects on Flexibility and Tunneling Pathways: The Rotational Spectrum of 2-Fluorobenzylamine ChemPhysChem 14

Version of Record online: 18 APR 2013 | DOI: 10.1002/cphc.201300121

Thumbnail image of graphical abstract

Bringing on a substitute: High-resolution spectral data in the gas phase coupled to theoretical calculations for 2-fluorobenzylamine (see picture) show that substitution of a single hydrogen atom with fluorine produces a change of structural and dynamical properties of the fluorine-substituted molecule relative to the unsubstituted form.

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