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Youngchan Park, Myungjin Lee and Prof. Hangil Lee Adsorption Sequence of Multifunctional Groups: A Study on the Reaction Pathway and the Adsorption Structure of Homocysteine on the Ge(100) Surface ChemPhysChem 14

Version of Record online: 31 MAY 2013 | DOI: 10.1002/cphc.201300124

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Who is first? The adsorption mechanism of homocysteine on a Ge(100) surface is investigated along with its electronic structures and adsorption geometries to determine the sequence of adsorption of this amino acid′s functional groups using core-level photoemission spectroscopy and density functional theory calculations. The “SH-dissociated OH-dissociated N-dative-bonded structure” is found to be the most stable structure.

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