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Natascia Turrà, Dr. Ulrich Neuenschwander and Prof. Dr. Ive Hermans Molecule-Induced Peroxide Homolysis ChemPhysChem 14

Version of Record online: 4 APR 2013 | DOI: 10.1002/cphc.201300130

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A radical is born: Evidence is provided that radicals are easily generated in a bimolecular reaction between alkyl hydroperoxide, the primary chain product during an auto-oxidation, and compounds featuring weak H atoms, such as olefins and dienes. Such compounds are therefore not only more reactive towards radicals; they also greatly assist in their formation.

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