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Dr. Goar Sánchez-Sanz, Prof. Ibon Alkorta, Dr. Cristina Trujillo and Prof. José Elguero Intramolecular Pnicogen Interactions in PHF[BOND](CH2)n[BOND]PHF (n=2–6) Systems ChemPhysChem 14

Version of Record online: 28 MAR 2013 | DOI: 10.1002/cphc.201300145

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The way to interact: A computational study of the intramolecular pnicogen bond in PHF[BOND](CH2)n[BOND]PHF (n=2–6) systems is carried out. For each compound, two different conformations, (R,R) and (R,S), are considered on the basis of the chirality of the phosphine groups. The characteristics of the closed conformers, in which the pnicogen interaction occurs, are compared with those of the extended conformer.

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