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Dr. Aditya Savara, Dr. Wiebke Ludwig and Dr. Swetlana Schauermann Kinetic Evidence for a Non-Langmuir-Hinshelwood Surface Reaction: H/D Exchange over Pd Nanoparticles and Pd(111) ChemPhysChem 14

Article first published online: 12 APR 2013 | DOI: 10.1002/cphc.201300179

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Tell me how: The mechanism of hydrogen recombination on a Pd(111) single crystal and well-defined Pd nanoparticles is studied using pulsed multi-molecular beam techniques and the H2/D2 isotope exchange reaction. It is found that various kinetic models are required to account for the observed phenomena.

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