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Dr. Walid M. Hikal and Dr. Brandon L. Weeks In Situ Direct Measurement of Vapor Pressures and Thermodynamic Parameters of Volatile Organic Materials in the Vapor Phase: Benzoic Acid, Ferrocene, and Naphthalene ChemPhysChem 14

Article first published online: 19 APR 2013 | DOI: 10.1002/cphc.201300182

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Reflections on vapor: A commercially available UV-spectrometer is used to determine absorption cross-sections, vapor densities, vapor pressures, and sublimation enthalpies of three reference materials in the vapor phase. The optical and thermodynamic properties are in agreement with the ICTAC recommended values with uncertainties of ∼5 and ∼1 % for vapor pressures and sublimation enthalpies.

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